Hexen-5-ol is an intermediate in he synthesis of 5-Chloro-1-hexene which is a reagent with difluoroacetic acid that results in the formation of 5-chloro-2-hexyl-2-d trifluoro-acetate and 1,4-chlorine shift.
Peterson, P. E., et al.: J. Am. Chem. Soc., 86, 4503-4 (1964)
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